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 by Staff Writers Berlin, Germany (SPX) Aug 23, 2021
Losses occur in all solar cells. One cause is the recombination of charge carriers at the interfaces. Intermediate layers at such interfaces can reduce these losses through so-called passivation. Self-assembled monolayers (SAMs) with a carbazole core are particularly well suited for the passivation of semiconductor surfaces made of perovskite materials. A team led by HZB physicist Prof. Steve Albrecht together with a group from Kaunas Technical University in Lithuania demonstrated this some time ago, developing a silicon-perovskite-based tandem solar cell with a record efficiency of over 29 %. Now, for the first time, a team at HZB has analysed the charge carrier dynamics at the perovskite/SAM-modified ITO interface in more detail. From time-resolved surface photovoltage measurements, they were able to extract the density of "electron traps" at the interface as well as the hole transfer rates using a minimalist kinetic model. Complementary information was provided by measuring the time-resolved photoluminescence. "We were able to determine differences in passivation quality, selectivity and hole transfer rates depending on the structure of the SAM, and demonstrate how the time-resolved surface photovoltage and photoluminescence techniques are complementary," explains Dr. Igal Levine, postdoc at HZB and first author of the paper. Time-resolved surface photovoltage proves to be a relatively simple technique for quantifying charge extraction at buried interfaces that could significantly facilitate the design of ideal charge-selective contacts.
Research Report: "Charge Transfer Rates and Electron Trapping at Buried Interfaces of Perovskite Solar Cells"
NASA spacewalk briefing to highlight new solar array installation Houston TX (SPX) Aug 20, 2021 Two astronauts will venture outside the International Space Station Tuesday, Aug. 24, for a spacewalk to install a support bracket in preparation for future installation of the orbiting laboratory's third new solar array. NASA will discuss the upcoming spacewalk during a news conference at 2 p.m. EDT Monday, Aug. 23. Live coverage of the news conference and spacewalk will air on NASA Television, the agency's website, and the NASA app. NASA astronaut Mark Vande Hei and astronaut Akihiko Hoshi ... read more
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